torsional strain sentence in Hindi
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- But many molecular biological processes can induce torsional strain.
- Angle strain and torsional strain combine to create ring strain that affects cyclic molecules.
- They occur at the flanks of transcribed regions, in 5?introns, and also at gene torsional strain.
- In mononuclear complexes with large m and n, the rings will rotate to reduce torsional strain within the linker arms.
- Torsional strain occurs when atoms separated by three bonds are placed in an eclipsed conformation instead of the more stable staggered conformation.
- This transannular strain, also known as Prelog strain, occurs when the cyclic molecules attempt to avoid angle and torsional strain.
- In this case torsional strain between the bulky tert-butyl group and the adjacent methylenes is relieved upon oxidation at C3.
- When the ring oxygen is not in the plane the substituents eclipse and when it is in the plane torsional strain is relieved.
- The B form of the DNA helix twists 360?per 10.4-10.5 bp in the absence of torsional strain.
- It was found that a combination of angle strain, torsional strain, and Pauli repulsion leads to the extreme destabilization experienced in this molecule.
- The above reaction is an example of the stereoelectronic selectivity-based strain relief ( alleviation of 1, 3-diaxial interactions, torsional strain, etc . ).
- Both conformations are free of torsional strain, but, in the gauche conformation, the two methyl groups are in closer proximity than the sum of their van der Waals radii.
- Further work has shown that the effect of 1, 3-dioxanes and 1, 3-dioxolanes on disarming sugars can be attributed to the electronics of the systems as well as torsional strain.
- Then follows a torsional strain relieving rotation to the trans isomer ( not shown ) and step "'C "'is a beta-hydride elimination step with the formation of a new palladium-alkene ? complex ( "'5 "').
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